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Question

The reactions of Cl2 gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two different oxoacids of chlorine, P and Q, respectively. The Cl2 gas reacts with SO2 gas, in presence of charcoal, to give a product R reacts with white phosphorus to give a compound S. On hydrolysis, S gives an oxoacid of phosphorus.

3. P and Q, respectively, are the sodium salts of


A

Hypochlorous and chloric acids

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B

Hypochlorous and chlorous acids

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C

Chloric and perchloric acids

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D

Chloric and hypochlorus acids

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Solution

The correct option is A

Hypochlorous and chloric acids


2NaOH+Cl2NaCl+NaClO+H2O
(Cold + dil.) P
6NaOH+3Cl25NaCl+NaClO3+H2O
(Hot + conc.) Q


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