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Question

The total number of stereoisomers that can exist for below compounds is:

A
4
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B
2
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C
3
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D
6
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Solution

The correct option is B 2
Although the compound has two chiral carbons, it does not has four optically active isomers as expected. It is due to its existence in cis-form only.
The compound does not show geometrical isomerism due to resticted rotation about the bridge head carbons, hence it remains in cis-form and only mirror image exists.


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