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Question

Total no. of reactions in which disproportion will occur.

(i)NO2+H2O(ii)Zn+Conc.HNO3(iii)WhiteP4+NaOH
(iv)HCHO+NaOHCannizaro reaction−−−−−−−−−−(v)FeSO4+NO3+H2SO4(vi)P4+SOCl2
(vii)H3PO3Δ(viii)I+S2O28(ix)MnO24H+(x)HNO2Δ


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Solution

(i)NO2+H2O2HNO3+NO(Dis) +4 +5 +2(ii)Zn+4HNO3Zn(NO3)2+2H2O+2NO2(iii)P4+3NaOH+3H2OPH3+3NaH2PO2(Dis)(iv)HCHOOHHCOO+CH3OH (Dis)(v)brown ring test

(vi)P4+SOCl24PCl3+4SO2+2S2Cl2(vii)4H3PO3Δ3H3PO4+PH3 (Dis)(viii)2I+S2O28I2+2SO4(ix)3MnO24+4H+2MnO4+MnO2+2H2O (Dis)(x)3HNO2HNO3+2NO+H2O (Dis)


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