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Question

Type of isomerism exhibited by [Cr(NCS)(NH3)5][ZnCl4] is :

A
coordination isomerism.
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B
linkage isomerism.
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C
ionization isomerism.
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D
both coordination and linkage isomerism.
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Solution

The correct option is D both coordination and linkage isomerism.
As -NCS and -SCN are isomer, both acts as ligand here, so linkage isomer due to this.
Also in this Cl and NCS can change coordinate sphere so coordination ismerism due to this.

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