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Question

What are the products of the following reaction?


A

No reaction happens. The substrate is unaffected

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B

The product is benzyl fluoride

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C

The major product is a nitrile attached to the benzene ring

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D

None of the above

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Solution

The correct option is B

The product is benzyl fluoride


18-crown-6 is an ether which traps K+ from KF and gets F to act as a nucleophile in a rare example.
CH3CN acts only as a solvent and does not take part in the reaction. So the product is:

This is a nifty method to synthesize alkyl fluorides.


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