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Question

What is correct order of size in each pair given below ?
Nb3+ and Ta3+

A
Nb3+ =Ta3+
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B
Nb3+ < Ta3+
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C
Nb3+ > Ta3+
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D
None of these
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Solution

The correct option is A Nb3+ =Ta3+
Option (A) is correct.
Nb3+ and Ta3+ have same order of size (ionic radii) as a consequence of lanthanoid contraction. They belong to group 5 (VB).

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