What is the appropriate reagent to carry out given synthesis, i.e., A, B, C respectively are.

B r_{2} / H^{+}, L i A l H_{4}, H^{\oplus}

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B r_{2} / H^{+}, N a B H_{4}, H O^{-}

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N B S, A l C l_{3}, H O^{-}

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B r_{2} / H O^{-}, B F_{3}, H O^{-}

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Solution

The correct option is B $B r_{2} / H^{+}, N a B H_{4}, H O^{-}$

Ketone tautomeries to only one side of carbon in the compound. It substitutes Bromine.
(Refer to Image)
(i) $B r, H^{+}$
(ii) $N a B H_{4}$
(iii) $O - H$

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The structure of D-(+)-mannose is:

The structure of L-(–)-mannose is:

S H^{-}, A c O^{-}, P h O^{-}, O H^{-}, H_{2} O

A g N O_{3}

N a B H_{4} / H_{3} O^{+}

N a B H_{4} / H_{3} O^{+}

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