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Question

What is the de Broglie wavelength of a nitrogen molecule in air at 300 K? Assume that the molecule is moving with the root-mean square speed of molecules at this temperature. (Atomic mass of nitrogen = 14.0076 u)

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Solution

Mass of N2=2×14.0076u=28.0152×1.66×1027kg
KE=3kT/2=mv2rms/2

vrms=3kT/m
de-broglie wavelength is, h/mvrms=0.028nm.

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