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Standard XII
Chemistry
Secondary Cells
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What will be the concentration of H+ in a solution if potential of hydrogen electrode is -118.2mV? (Partial pressure of H2 is 1 atm)
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Q.
The potential of hydrogen electrode at
25
o
C
will be:
(
P
H
2
=
1
atm, concentration of
H
+
=
0.1
M
)
Q.
At what pH of HCl solution will hydrogen gas electrode show electrode potential of
−
0.118
V
H
2
gas is bubbled at 298 K and 1 atm pressure?
Q.
If the pressure of
H
2
gas is increased from
1
atm to
100
atm keeping
H
+
concentration constant at
1
M
, the change in reduction potential of hydrogen half cell at
25
o
C
will be:
Q.
The potential of hydrogen electrode is
−
118.5
mV. The
H
+
concentration of the solution is:
Q.
Calculate the reversible potential of oxygen electrode in a solution of
p
H
=
1
, when the partial pressure of
O
2
is
10
−
2
atm [Assume
E
0
O
2
/
H
2
O
=
1.23
V. vs SHE at
1
atm and
25
o
C]
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