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Question

Which has highest dipole moment?

A
2,2-dimethyl propane
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B
trans-2-pentene
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C
cis-3-hexene
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D
2,2,3,3-tetramethyl butane
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Solution

The correct option is B cis-3-hexene
2,2-dimethyl propane and 2,2,3,3-tetramethyl butane are symmetrical alkanes. They have zero dipole moment.
The dipole moment of cis-3-hexene is maximum as the dipole moment of cis alkene is higher than trans alkene.
In symmetrical trans alkene, the dipole moment is zero due to symmetry.
Trans-2-pentene is unsymmetrical trans alkene and has some dipole moment. But its dipole moment is lower than that of cis-3-hexene.

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