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Byju's Answer
Standard XII
Chemistry
Collision Theory
Which is wron...
Question
Which is wrong about a positive catalyst?
A
It lowers the energy of activation of forward reaction
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B
It lowers the threshold energy level
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C
It lowers the energy of activation of backward reaction
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D
It makes the reaction more exothermic or endothermic
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Solution
The correct option is
C
It makes the reaction more exothermic or endothermic
Catalyst cannot make the reaction more exothermic or endothermic.
Δ
H
=
E
a
(
f
)
−
E
a
(
b
)
is fixed for a reaction since catalyst change the activation by equal magnitude in both forward and backward reaction.
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Assertion :Positive catalyst lowers the activation energy of the reaction whereas the heat of reaction remains same. Reason: The heat of reaction is equal to the difference between activation energies for forward and backward reactions.
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If the reactants are at a higher energy level than products, the reaction is exothermic. The activation energy of a forward reaction is less than that of the backward reaction. That means, the energy required for breaking of bonds is less than the energy released during formation of bonds. In case of an endothermic reaction, the activation energy of the forward reaction is more than that of backward reaction.
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For an endothermic reaction, the correct statement about the energy of activation for forward and backward reaction is:
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Assertion :Positive catalysts lower the activation energy of the reaction whereas heat of reaction remains same. Reason: Heat of reaction is equal to the difference between activation energies for forward and the backward reactions.
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