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Question

Which of following are correctly matched?

A
PhCOOH to PhNH2: Convert to amide and use Hoffmann bromamide reaction
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B
CH3CH2OH to CH3CH2CH2NH2: Nucleophilic substitution with cyanide and reduce the compound
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C
CH3CH=CHCH3 to CH3NH2: Use Schmidt reaction on the alkene
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D
Both A and B
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Solution

The correct option is C Both A and B
(A)PhCOOHSOCl2−−−PhCOClNH3−−PhCONH2Br2/KOH−−−−−PhNH2

(B)CH3CH2OHSOCl2−−−CH3CH2ClKCN−−CH3CH2CNH2/Ni−−−CH3CH2CH2NH2

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