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Question

Which of the following 0.10 m aqueous solutions will have the lowest freezing point?

A
Al2(SO4)3
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B
KI
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C
C6H12O6
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D
C12H22O11
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Solution

The correct option is A Al2(SO4)3
There is a depression in freezing point of a solvent when a non-volatile solute is added to it.
ΔTf=iKfm
Since the molality is given, we need to look at the i value of the options to get the answer.
Al2(SO4)3 will have the greatest value of van 't Hoff factor (i=5), its solution would have the lowest freezing point.

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