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Hinsberg Test

Which of the ...

Question

Which of the following amines does not react with Hinsberg reagent?

C H_{3} C H_{2} - N H_{2}

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C H_{3} - N H - C H_{3}

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(C H_{3} C H_{2})_{3} N

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All of these

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Solution

The correct option is C $(C H_{3} C H_{2})_{3} N$
$(C H_{3} C H_{2})_{3} N$ : N,N-diethylethanamine is a tertiary amine.

Tertiary amines ( $R_{3} N$ ) does not react with Hinsberg reagent ( $C_{6} H_{5} S O_{2} C l$ ) as there are no freely available Hydrogens on the amine group which can donate electrons to the Sulphur of the Hinsberg reagent.

Option C is correct.

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