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Chlorination

Which of the ...

Question

Which of the following are formed on addition reaction of DCI with 3-methyl-1-butene

A

C H_{2} D C H C l C H (C H_{3})_{2}

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B

C H_{2} D C H_{2} C C l (C H_{3})_{2}

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C

C H_{3} C D C l C H (C H_{3})_{2}

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D

C l C H_{2} C H D C H (C H_{3})_{2}

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Solution

The correct options are
A $C H_{2} D C H C l C H (C H_{3})_{2}$
C $C H_{3} C D C l C H (C H_{3})_{2}$
Markovnikov's addition yields $C H_{2} D C H C l C H (C H_{3})_{2}$ and $C H_{3} C D C l C H (C H_{3})_{2}$

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