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Question

Which of the following can not be used in Fridel craft reaction?

A
Methylbenzene
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B
Methoxybenzene
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C
Nitrobenzene
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D
Chlorobenzene
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Solution

The correct option is D Methylbenzene
(C) Nitrobenzene, since it has NO2 group which is highly deactivating group, and it decreases ¯¯¯e density from ring preventing electrophilic attack on ring.

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