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Question

Which of the following compounds has lowest boiling point ?

A
n-butyl alcohol
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B
Isobutyl alcohol
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C
Tert-butyl alcohol
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D
Sec-butyl alcohol
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Solution

The correct option is C Tert-butyl alcohol
Tert-butyl alcohol has lowest boiling point.

As the number of carbon same and same molecular formula i.e. same molar mass.

With increase in the degree of branching, the boiling point decreases.

Option C is correct.

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