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Question

Which of the following compounds will give acetic acid with KMnO4/H/Δ:

A
CH3CHO
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B
CH3CH=CHCH3
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C
CH3CCCH3
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D
CH3CH2OH
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Solution

The correct options are
A CH3CHO
B CH3CH=CHCH3
C CH3CCCH3
D CH3CH2OH
Ethanol is oxidized to acetaldehyde on treatment with acidified potassium permanganate. Acetaldhyde is further oxidized to acetic acid.
Acidified potassium permanganate also breaks carbon carbon double bonds and triple bonds. Two carbons attached to multiple bond are oxidized to carboxylic group.
Thus the compounds of all the four options on oxidation with acidified potassium permanganate gives acetic acid.

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