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Central Atom and Ligands

Which of the ...

Question

Which of the following has highest conductivity?

K_{2} [P t C l_{6}]

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K_{4} [F e (C N)_{6}]

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[C o (N H_{3})_{6}] C l_{3}

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[C o (N H_{3})_{3} (N O_{2})_{3}]

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Solution

The correct option is B $K_{4} [F e (C N)_{6}]$
The maximum conductivity of a complex depends on the number of ions it produces in a solution.The complex $K_{4} [F e (C N)_{6}]$ produces $4 K^{+}$ and $[F e (C N)_{6}]^{4 -}$ i.e total of 5 ions which is maximum among the given complexes. Hence the correct option is B.

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