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Question

Which of the following is not correct?

A
Hydrolysis of NCl3 gives NH3 and HOCl
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B
NH3 is less stable than PH3
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C
NH3 is a weak reducing reagent compared to PH3
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D
Nitric oxide in solid state exhibits diamagnetic property.
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Solution

The correct option is D NH3 is less stable than PH3
Bond energy in nitrogen hydride is more than in phosphorous hydride. So, ammonia is more stable than phosphorous hydride.

Hydrolysis of NCl3 gives ammonia.

NCl3+3H2ONH3+3HOCl

Nitric oxide NO exhibits diamagnetic property because of dimerisation.

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