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Question

Which of the following is the chain propagation step in chlorination of methane?

A
CH3+ClCH3Cl
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B
CH3+ClClCH3Cl+Cl
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C
ClClCl+Cl
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D
Cl+ClCl2
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Solution

The correct option is C CH3+ClClCH3Cl+Cl
Chain initiation
Cl2h2˙Cl+C˙l
chain propagation:
CH3+ClClCH3Cl+C˙l
CH3Cl+ClClCH2Cl+C˙l
CH2Cl2+ClClCHCl3+C˙l
CHCl3+ClCl CCl4+C˙l

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