Which of the following is the correct match considering column-I and column-II?

(A-S), (B-R), (C-Q), (D-P)

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(A-R), (B-S), (C-P), (D-Q)

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(A-S), (B-R), (C-P), (D-Q)

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(A-R), (B-S), (C-Q), (D-P)

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Solution

The correct option is B (A-R), (B-S), (C-P), (D-Q)
Rate of solvolysis depends upon the stability of carbocation. More stable is the carbocation, greater will be the rate of solvolysis.
Order of stability of carbocations:

$∴$ Correct match is: (A-R), (B-S), (C-P) and (D-Q)

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