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Question

Which of the following is the correct order of basic strength of amines in aqueous medium.
  1. (CH3)3N > (CH3)2NH  > CH3NH2
  2. (CH3)2NH > CH3NH2 > (CH3)3N
  3. (CH3)2NH > (CH3)3N > (CH3)NH2
  4. (CH3)3N > CH3NH2 > (CH3)2NH


Solution

The correct option is B (CH3)2NH > CH3NH2 > (CH3)3N
For methyl amines the correct order is 2 > 1 > 3 due to solvation and inductive effects.

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