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Question

Which of the following is the strongest base?

A
AsH3
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B
NH3
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C
PH3
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D
SbH3
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Solution

The correct option is B NH3
In the hydrides of group 15, the basic character decreases down the group. NH3 is the strongest electron pair donor due to its' small size as the electron density of the electron pair is concentrated over a small region. As the size increases, the electron density gets diffused over a large region and hence the ability to donate the electron pair decreases. Therefore, the basic nature decreases.
So strongest base is NH3.
Hence option B is correct.

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