The correct option is A Mn
The ground state electronic configuration of Mn
=[Ar]4s23d5
So number of unpaired electrons in Mn = 5
The ground state electronic configuration of Fe
=[Ar]4s23d6
So number of unpaired electrons in Fe = 4
The ground state electronic configuration of Sc
=[Ar]4s23d1
So number of unpaired electrons in Sc = 1
The ground state electronic configuration of V
=[Ar]4s23d3
So number of unpaired electrons in V = 3
Thus, Mn has the most number of unpaired electrons.