Which of the following reaction can produce aniline as main product?

C_{6} H_{5} N O_{2} + Z n / K O H

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C_{6} H_{5} N O_{2} + Z n / N H_{4} C l

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C_{6} H_{5} N O_{2} + L i A I H_{4}

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C_{6} H_{5} N O_{2} + Z n / H C l

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Solution

The correct option is A $C_{6} H_{5} N O_{2} + Z n / K O H$
$C_{6} H_{5} N O_{2} + 6 H Z n / K O H - ----- \to C_{6} H_{5} N H_{2}$
$\frac{Z n}{K O H}$ is a reducing agent which gives $6$ hydrogens. So, it results in conversion of Nitrobenzene into aniline.

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C_{6} H_{5} N O_{2} C l_{2} / F e - --- \to

C_{6} H_{6} +^{'} X^{'} . . . . \to C_{6} H_{5} N O_{2}

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C_{6} H_{5} N O_{2} \to C_{6} H_{5} N H_{2}

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