Which of the following reaction will give diastereomers as the product(s)?
A
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B
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C
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D
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Solution
The correct options are A D (a) Bayer's reagent performs syn dihydroxylation and the products obtains are diastereomers (non superimposible). (b) Br2/CCl4 adds to alkene via anti orientation. Here, the products are a pair of enantiomers. (c) Products obtained are a pair of enantiomers after the anti-addition of Cl2 (in CCl4) to the given alkene. (d) Anti-addition leads to the formation of diastereomers.