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Question

Which of the following reactions follows Markovnikovs rule?

A
C2H4+HBr
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B
C3H6+Cl2
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C
C3H6+HBr
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D
CH6+Br2
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Solution

The correct option is D C3H6+HBr
When HBr is added to an alkene in the absence of peroxides it obey Markovnikovs rule. When HBr reacts with unsymmetrical alkene in the presence of peroxides HBr adds in the opposite direction to that predicted by Markovnikov's rule.
CH3CH=CH2+HBr

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