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Reductions Involving Aldehydes or Ketones

Which of the ...

Question

Which of the following reagent can be used for following conversion?

-

Hg/HCl

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Red P

+

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N H_{2} - N H_{2}

^{⊖} O H

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All of them

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Solution

The correct option is D All of them
$Z n - H g / H C l$ , $R e d p + H I$ and $N H_{2} - N H_{2} / O H^{-}$ are all strong reducing agents and reduces alcohol,ketones and aldehydes to hydrocarbons.

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(O H)

(- {N H}_{2})

({N O}_{2}^{-})

({N O}_{3}^{-})

{N H}_{4} C l

({N H}_{2})_{2} C S

{N H}_{2} {S O}_{3} H

What is the decreasing order of strengths of the following bases?
$⊖ O H, N H_{2}^{⊖}, H - C \equiv C^{⊖}, a n d C H_{3} - C H_{2}^{⊖}$

(N H_{2}^{-}, C H_{3} C O O^{-}, O H^{-})

i) I_{2} / N a O H i i) C r O_{3}

i i i) Tollens' reagent i v) L i A I H_{4}

v) N a B H_{4} v i) mCPBA

v i i) S e O_{2} / Δ v i i i) N H_{2} - N H_{2} / p H (4 - 6)

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