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Valence Bond Theory

Which of the ...

Question

Which of the following statements is correct for $[M n (C N)_{6}]^{3 -}$ according to valence bond theory?

d^{2} s p^{3}

, inner orbital complex, paramagnetic, 2.87 B.M.

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d^{2} s p^{3}

, inner orbital complex, diamagnetic, zero magnetic moment.

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d^{2} s p^{3}

, outer orbital complex, paramagnetic, 3.87 B.M.

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d s p^{2}

, outer orbital complex, diamagnetic, zero magnetic moment.

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Solution

The correct option is A $d^{2} s p^{3}$ , inner orbital complex, paramagnetic, 2.87 B.M.
In $[M n (C N)_{6}]^{3 +}$ , oxidation state of Mn = +3,

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Which of the following inner orbital octahedral complex ions are diamagnetic?

\sqrt{n (n + 2)}

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