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Question

Which of the following will have the highest number of neutrons at STP?

A
22.4 L of CO2
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B
11.2 L N2
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C
112 L H2
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D
89.6 L He
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Solution

The correct option is A 22.4 L of CO2
For calculating the number of neutrons, we must find the number of moles in each sample.
Moles of CO2=given volumemolar volume at STP=22.422.4=1 mole
Moles of N2=given volumemolar volume at STP=11.222.4=0.5 mole
Moles of H2=given volumemolar volume at STP=11222.4=5 mole
Moles of He=given volumemolar volume at STP=89.622.4=4 mole

1 molecule of CO2 has 6+2(8) neutrons = 22 neutrons
Therefore, 1 mole of CO2 will have 22NA neutrons.
1 molecule of N2 has 14 neutrons.
So, 0.5 moles will have (0.5×14NA)=7NA neutrons.
Hydrogen molecule does not have any neutrons
1 molecule of He has 2 neutrons.
So, 4 moles of He will have (4×2NA)=8NA neutrons

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