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Question

Which one of the following complexes is not expected to exhibit isomerism?

A
[Ni(NH3)4(H2O)2]2+
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B
[Pt(NH3)2Cl2]
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C
[Ni(NH3)2Cl2]
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D
[Ni(en)3]2+
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Solution

The correct option is C [Ni(NH3)2Cl2]
Compounds having tetrahedral geometry does not exhibit isomerism due to presence of symmetry elements. Here, [Ni(NH3)2Cl2] has tetratedral geometry.

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