The correct option is D Fe2+
No of unpaired electron in different ions are as under :
Mg2+→1s2,2s22p6,3s0=0 Unpaired electron
Ti3+→1s2,2s22p6,3s23p63d1,4s0=1 Unpaired electron
V3+→1s2,2s22p6,3s23p63d2,4s0=2 Unpaired electron
Fe2+→1s2,2s2sp6,3s23p63d6,4s0=4 Unpaired electron
option d is the correct answer