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Question
Which one of the following on reduction with LiAlH4 yields a secondary amine?
Which one of the following on reduction with LiAlH4 yields a secondary amine?
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Solution
The correct option is C Methyl isocyanide
On catalytic reduction or with lithium aluminium hydride (LiAlH4) or with nascent hydrogen, alkyl isocyanide yield 2∘ amine whereas cyanide gives 1∘ amine on reduction.hence c is correct answer
On catalytic reduction or with lithium aluminium hydride (LiAlH4) or with nascent hydrogen, alkyl isocyanide yield 2∘ amine whereas cyanide gives 1∘ amine on reduction.
hence c is correct answer
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