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Preparations and Reactions of Sodium Oxide

Which one of ...

Question

Which one of the following reactions is not associated with the Solvay process of manufacture of sodium carbonate?

N a C l + N H_{4} C O_{3} \to N a H C O_{3} + N H_{4} C l

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2 N a O H + C O_{2} \to N a_{2} C O_{3} + H_{2} O

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2 N a H C O_{3} \to N a_{2} C O_{3} + H_{2} O + C O_{2}

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N H_{3} + H_{2} C O_{3} \to N H_{4} H C O_{3}

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Solution

The correct option is B $2 N a O H + C O_{2} \to N a_{2} C O_{3} + H_{2} O$
Solvay Process:
$2 N H_{3} + H_{2} O + C O_{2} \to (N H_{4})_{2} C O_{3}$
$(N H_{4})_{2} C O_{3} + C O_{2} + H_{2} O \to 2 N H_{4} H C O_{3}$
$N H_{4} H C O_{3} + N a C l \to N H_{4} C l + N a H C O_{3}$
$2 N a H C O_{3} \to N a_{2} C O_{3} + H_{2} O + C O_{2}$

Hence,option B is correct.

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2 N H_{3} + H_{2} O + C O_{2} ⟶ (N H_{4})_{2} C O_{3} (a q) (a) ⟶ N H_{4} H C O_{3} (b) ⟶ N a H C O_{3} ↓ (d) N a_{2} C O_{3} + C O_{2} + H_{2} O + (c)

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