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Question

Which will liberate bromine from a solution of potassium bromide?

A
I2
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B
Cl2
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C
SO2
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D
HI
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Solution

The correct option is D Cl2
Chlorine is more reactive than bromine and it displaces bromine.
If chlorine is added to a solution of potassium bromide, the bromine is replaced by the chlorine forming potassium chloride. Bromine is formed at the same time and can be detected by its colour.

2KBr+Cl22KCl+Br2

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