X and
Y are two volatile liquids with molar weights of
10 g mol−1 and
40 g mol−1 respectively. Two cotton plugs are soaked in
X and other soaked in
Y are simultaneously placed at the ends of a tube of length
L=24 cm, as shown in the figure. The tube is filled with an inert gas at
1 atm pressure and temperature of
300 K. The vapour of
X and
Y react to form a product which is first observed at a distance
d cm from the plug soaked in
X. Take
X and
Y to have equal molecular diameters and assume ideal behaviour for the inert gas and the two vapours.
The value of d in cm as estimated from Graham's law is: