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Question

What is a cell with positive E°cell?


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Solution

Understanding the concept:

  • A cell is the source of energy that generates electric current through chemical reactions.

Explanation of positive E°cell:

  • The reaction will move forward if E° (the redox reaction) is positive (spontaneous).
  • It is possible to generate electricity by a spontaneous process.
  • One type of electrochemical cell, the galvanic cell (also known as the voltaic cell), transforms the chemical energy of oxidants & reductants into electrical energy.
  • Electricity can only be created if a redox reaction is spontaneous
  • For a typical standard galvanic cell (voltaic cell), E° is positive, meaning that E°(cell) > 0
  • E°(cell), also known as the standard potential difference of a cell or electromotive force (emf), is the highest voltage that a redox cell is capable of producing.

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