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Question

What is polarizing power and polarizability?


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Solution

Fajan's rule

  • Fajan's rule is based on the concept of polarization, which claims that the covalent nature of an anion rises as its polarization increases.
  • The polar strength of the cation and the anion's polarizability are the two main parameters that influence the extent of polarization of an anion.

Polarizing power

  • The polarizing power of a cation is defined as its ability to distort an anion.
  • For example, the polarizing power of sodium ion Na+ distorts chlorine electrons and attracts them to the sodium atom.

Polarizability

  • Polarizability is defined as the anion's susceptibility to getting polarized by the cation.
  • An ionic bond is formed when the degree of polarization is extremely low, whereas a covalent bond is formed when the degree of polarization is very high.

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