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Question

What is the intermediate formed in homolytic fission?


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Solution

Homolytic fission:

  • “In homolytic cleavage, one of the electrons of the shared pair in a covalent bond goes with each of the bonded atoms.”
  • It involves the movement of a single electron. The single electron movement is shown by the ‘half-headed’ arrow.
  • This fission results in the formation of free radicals that are neutral species with an unpaired electron.
  • Homolytic fission can be shown as:

Thus, the intermediate that is formed in homolytic fission is free radicals.


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