Crystal Structure

What is Crystal Structure?

A crystal structure is made of atoms. A crystal lattice is made of points. A crystal system is a set of axes. In other words, the structure is an ordered array of atoms, ions or molecules.

Crystal Structure is obtained by attaching atoms, groups of atoms or molecules. This structure occurs from the intrinsic nature of the constituent particles to produce symmetric patterns. A small group of a repeating pattern of the atomic structure is known as the unit cell of the structure. A unit cell is the building block of the crystal structure and it also explains in detail the entire crystal structure and symmetry with the atom positions along with its principal axes. The length, edges of principal axes and the angle between the unit cells are called lattice constants or lattice parameters.

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Unit Cell

Crystals use x-rays, which excite signals from the atom. The signals given by these atoms have different strengths, and they usually depend upon the electron density distribution in closed shells. The signals released by the atoms varies. Lighter the atoms, weaker is their signals. The mutual arrangement of atoms is also known as crystal structures. Crystal structures are derived from the physical density and chemical formulas of solids.

Crystal Structure

Unit cell can be defined as the smallest part of a component of the crystal. A group of atoms, ions or molecules, which are arranged together in a pure manner to build the crystal. The unit cells are structured in three-dimensional space, which describes the bulk arrangement of atoms of the crystal.

Sodium Chloride Crystal Structure

Sodium Chloride Crystal Structure

Crystal Systems

A Crystal System refers to one of the many classes of crystals, space groups, and lattices. In crystallography terms, lattice system and crystal, the system are associated with each other with a slight difference. Based on their point groups crystals and space groups are divided into seven crystal systems.

The Seven Crystal Systems is an approach for classification depending upon their lattice and atomic structure. The atomic lattice is a series of atoms that are organized in a symmetrical pattern. With the help of the lattice, it is possible to determine the appearance and physical properties of the stone. It is possible to identify to which crystal system they belong to. In a Cubic System crystals are said to represent the element earth. They are Seven Crystal Systems and are stated below with illustrated examples.

The Seven Crystal Systems

  1. Triclinic System:

    All three axes are inclined towards each other, and they are of the same length. Based on the three inclined angles the various forms of crystals are in the paired faces. Some standard Triclinic Systems include Labradorite, Amazonite, Kyanite, Rhodonite, Aventurine Feldspar, and Turquoise.

    Triclinic System

    Triclinic System

  2. Monoclinic System:

    It comprises three axes where two are at right angles to each other, and the third axis is inclined. All three axes are of different length. Based on the inner structure the monoclinic system includes Basal pinacoids and prisms with inclined end faces. Some examples include Diopside, Petalite, Kunzite, Gypsum, Hiddenite, Howlite, Vivianite and more.

    Monoclinic System

    Monoclinic System

  3. Orthorhombic System:

    It comprises three axes and is at right angles to each other. There are different lengths. Based on their Rhombic structure the orthorhombic system includes various crystal shapes namely pyramids, double pyramids, rhombic pyramids, and pinacoids. Some common orthorhombic crystals include Topaz, Tanzanite, Iolite, Zoisite, Danburite and more.

    Orthorhombic System

    Orthorhombic System

  4. Trigonal System:

    Angles and axis in a trigonal system are similar to Hexagonal Systems. At the base of a hexagonal system (ross-section of a prism), there will be six sides. In the trigonal system (base cross-section) there will be three sides. Crystal shapes in a trigonal system include three-sided pyramids, Scalenohedral and Rhombohedra. Some typical examples include Ruby, Quartz, Calcite, Agate, Jasper, Tiger’s Eyes and more.

    Trigonal System

    Trigonal/Pyramidal System

  5. Hexagonal System:

    It comprises four axes. Among them, three axes are of the same length and are on one plane. They intersect each other at an angle of sixty degrees. The fourth axis intersects other axes at right angles. Crystal shapes of hexagonal systems include Double Pyramids, Double-Sided Pyramids, and Four-Sided Pyramids. Example: Beryl, Cancrinite, Apatite, Sugilite, etc.

    Hexagonal System

    Hexagonal System

  6. Tetragonal Systems:

    It consists of three axes. The main axis varies in length; it can either be short or long. The two-axis lie in the same plane and are of the same length. Based on the rectangular inner structure the shapes of crystal in tetragonal include double and eight-sided pyramids, four-sided prism, trapezohedrons, and pyrite.

    Tetragonal Systems

    Perovskite – Tetragonal Systems

  7. Cubic System:

    All three angles intersect at right angles and are of equal length. Crystal shapes of a cubic system based on inner structure (square) include octahedron, cube, and Hexaciscoherdron. Example: Silver, Garnet, Gold, and Diamond.

    Cubic System

    Cubic System

To know more about the Atomic Structure, Crystal structure, and their classification, register with BYJU’S.

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