Polarity

Define Polarity

“A state or a condition of an atom or a molecule inherent in a body that exhibits opposite properties or powers in opposite parts or directions.”

Polarity, in general, refers to the physical properties of compounds such as boiling point, melting points, and their solubilities. The polarity of bonds mainly arises from the act between molecules and atoms with various electronegativities.

Polarity is the distribution of electrical charge among the atoms connected by a chemical bond. Because both hydrogen atoms in H2 are electrically neutral, bonds between atoms of different elements are electrically inequivalent, as opposed to bonds between identical atoms, which are electrically uniform.

Polarity

Moving on, usually, the term Polarity is used in areas like magnetism, electricity, and signalling of electronic devices. Consider an electromotive force (EMF) or an electric potential, acting between two points. Here the points or poles as they are commonly known as have more electrons than the other. The pole having more electrons possesses a negative polarity whereas the other end has a positive polarity.

Talking about polarity in Chemistry, well it is basically the separation of an electric charge which leads a molecule to have a positive and negative end.

Consider the below example.

Hydrogen Fluoride

In an H-F bond, the fluorine atom is said to be more electronegative than the Hydrogen atom. The electrons eventually spend more time at the Fluorine atom. Hence, this F atom slightly becomes negative whereas the Hydrogen atom tends to become slightly positive.

Polarity of Molecules

The bond or the molecular polarities depend upon the electronegativities of the atoms or the molecules. A molecule is basically said to be either a polar molecule, non- polar molecule or ionic molecule.

  • Polar Molecules: A polar molecule is usually formed when the one end of the molecule is said to possess more positive charges and whereas the opposite end of the molecule has negative charges, creating an electrical pole. When a molecule is said to have a polar bond, then the centre of the negative charge will be on one side, whereas the centre of positive charge will be in the different side. The entire molecule will be a polar molecule.
  • Non- Polar Molecules: A molecule which does not have the charges present at the end due to the reason that electrons are finely distributed and those which symmetrically cancel out each other are the non- polar molecules. In a solution, a polar molecule cannot be mixed with the non-polar molecule. For example, consider water and oil. In this solution, water is a polar molecule whereas oil behaves as a non-polar molecule. These two molecules do not form a solution as they cannot be mixed up.

Examples of Polar and Non-Polar Molecules 

A molecule may be polar or non-polar. A non-polar molecule has a structure of its atoms lined up in a way that the orbital electrons in the outer region cancel out the electronegativity.

  • In general, pyramid-shaped and V-shaped molecules are said to be polar. Whereas the Linear molecules are said to be non-polar in nature.
  • Water is said to be a polar molecule due to the difference in the electronegativities between the oxygen atom and the hydrogen. Oxygen is a highly electronegative atom when compared to hydrogen.
  • Fats, petrol, oil, and gasoline are said to be non-polar molecules as they do not dissolve in water and nonpolar is insoluble in water.
  • Glucose is one more example of a polar molecule based on the arrangement of the oxygen and hydrogen atoms in it.

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Frequently Asked Questions – FAQs

Q1

What does polarity mean in chemistry?

The distribution of electrical charge over the atoms connected by the bond is referred to as polarity in chemical bonding. For example, the hydrogen atom in hydrogen chloride is slightly positively charged, whereas the chlorine atom is slightly negatively charged.

Q2

What causes polarity?

The distribution of electrical charge over the atoms connected by the bond is referred to as polarity in chemical bonding. For example, the hydrogen atom in hydrogen chloride is slightly positively charged, whereas the chlorine atom is slightly negatively charged.

Q3

What is positive and negative polarity?

Negative polarity is defined as the pole having the most electrons. Positive polarity is assigned to the pole with the fewest electrons. Electrons move from the negative pole to the positive pole when the two poles are linked by a wire. An electric current is the name for this flow.

Q4

What is polar and nonpolar solvents?

Polar solvents include bonds between atoms with highly differing electronegativities, such as oxygen and hydrogen, and have significant dipole moments (also known as “partial charges”). Bonds between atoms with comparable electronegativities, such as carbon and hydrogen, exist in non-polar fluids.

Q5

Is acetone polar or nonpolar?

Acetone is a polar molecule since it possesses a polar bond and the dipole is not cancelled by the molecular structure.

Test Your Knowledge On Polarity!

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  1. good learning app thanks

  2. Really helpful
    Thank you so much!