Electronegativity

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What is Electronegativity? Periodic Trends in Electronegativity Electronegativity Table Factors Affecting Electronegativity FAQs

What is Electronegativity?

The tendency of an atom in a molecule to attract the shared pair of electrons towards itself is known as electronegativity.

It is a dimensionless property because it is only a tendency. It basically indicates the net result of the tendencies of atoms in different elements to attract the bond-forming electron pairs. We measure electronegativity on several scales. The most commonly used scale was designed by Linus Pauling. According to this scale, fluorine is the most electronegative element with a value of 4.0 and cesium is the least electronegative element with a value of 0.7.

Check out the electronegativity values of elements in the electronegativity chart.

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Electronegativity Trend in Periodic Table

As we move across a period from left to right the nuclear charge increases and the atomic size decreases, therefore the value of electronegativity increases across a period in the modern periodic table. For example, the electronegativity trend across period 3 in the periodic table is depicted below.

Electronegativity trend across the period

Electronegativity Trend – Across the Period

There is an increase in the atomic number as we move down the group in the modern periodic table. The nuclear charge also increases but the effect of the increase in nuclear charge is overcome by the addition of one shell. Hence the value of electronegativity decreases as we move down the group. For example, in the halogen group as we move down the group from fluorine to astatine the electronegativity value decreases and it is shown in the diagram below.

Electronegativity Trend Down the Group

Electronegativity Trend – Down the Group

It is a general observation that metals show a lower value of electronegativity as compared to the non-metals. Therefore metals are electropositive and non-metals are electronegative in nature. The elements in period two differ in properties from their respective group elements due to the small size and higher value of electronegativity.

The elements in the second period show resemblance to the elements of the next group in period three. This happens due to a small difference in their electronegativities. This leads to the formation of a diagonal relationship.

Most and Least Electronegative Elements

Fluorine is the most electronegative element on the periodic table. Its electronegativity value is 3.98. Cesium is the least electronegative element. Its electronegativity value is 0.79. Electropositivity is the exact opposite of electronegativity, therefore, we can say that Cesium is the most electropositive element.

Those elements requiring only a few electrons to complete their valence shells, and having the least quantity of inner electron shells between the positive nucleus and the valence electrons, are the most electronegative. The most electronegative of all elements are fluorine. Its electronegativity is 4.0. Metals have electronegativities less than 2.0. The least electronegative elements are cesium (Cs) and francium (Fr), with electronegativity values of 0.7.

Therefore,

Fluorine is the most electronegative element and cesium is the least electronegative element.

Electronegativity Table

Electronegativity is a chemical property that describes the power of an atom in a molecule to attract electrons to itself. There is a large difference in electronegativity for atoms from the left- and right-hand sides of the periodic table. Electronegativity is an important quantity in determining the nature of bonds between elements and will be considered as the main factor in chemical bonding.

The periodic table of elements with the electronegativity table is given below.

Electronegativity Table

Electronegativity Values – Periodic Table of Elements

Factors Affecting Electronegativity

1. Size of an Atom:

A greater atomic size will result in less value of electronegativity, this happens because electrons being far away from the nucleus will experience a lesser force of attraction.

2. Nuclear Charge:

A greater value of nuclear charge will result in a greater value of electronegativity. This happens because an increase in nuclear charge causes electron attraction with greater force.

3. Effect os Substituent:

The electronegativity of an atom depends upon the nature of substituent attached to that atom. For example, the carbon atom in CF3I acquires a greater positive charge than CH3I. Therefore, C-atom in CF3I is more electronegative than in CH3I. The difference in electronegativity of an atom caused by substituents results in different chemical behavior of that atom.

Frequently Asked Questions

Which is the best definition of electronegativity?

Electronegativity is a function of an atom’s ability to attract an electrons binding pair. The most frequently used is the Pauling scale. Fluorine is assigned a value of 4.0, and values that are the least electronegative at 0.7 range down to cesium and francium.

What is high electronegativity?

Electronegativity decreases in classes from bottom to top and increases over time from left to right. The most electronegative element is, therefore, fluorine, while francium is one of the least electronegative elements.

What is the electronegativity difference?

The degree to which an atom attracts electrons in a chemical bond is described by electronegativity. If the difference in electronegativity is greater than 1.7, the character of the bond will be ionic. If the difference in electronegativity is between 0.4 and 1.7, the character of the bond is polar covalent.

What is the difference between electron affinity and electronegativity?

The difference between the two is that electronegativity is a chemical property that shows how well an atom can attract electrons to itself as the amount of energy released when an electron is added to a neutral atom.

Is electronegativity a relative quantity?

Electronegativity is an example of an atom’s ability to attract electrons. It is proportional to the difference between the potential for ionization of an atom and its attraction to the electron.

This article has briefly described the concept of electronegativity. For any query on this topic install BYJU’S – the learning app.

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