Rusting Of Iron & Rust Prevention

Have you ever witnessed an old car or a train-body or a sunken ship which has been dumped in a junkyard for years? If so, you might have noticed a reddish- or yellowish-brown flaking coating formed on their surface. This is because the metal has corroded at those spots and the process is called rusting.

Rusting

What is Corrosion?

Corrosion is a gradual deterioration of metals upon interaction with the environment as a result of chemical reactions between them. Almost every metal is susceptible to degradation. Rusting of iron is the most familiar example of corrosion.

What is Rust?

When iron is exposed to water or air over a period of time, the iron reacts with oxygen in the presence of moisture to form a reddish-brown chemical compound, iron oxide. This is referred to as rust. So chemically, rust is hydrated iron(III) oxide or Fe2O3.nH2O. The chemical equation for the same is given by:

4Fe(OH)2 + O2 + xH2O → 2Fe2O3.(x+4)H2O

Iron reacts very readily with oxygen. This is one of the reasons as to why it is rare to find pure iron in nature.

Factors Affecting Rusting

There are several factors that assist and accelerate the process of rusting. Some of them are:

  • Moisture: Iron exposed to rains is the most common reason.
  • Acid: It accelerates rusting. When exposed to acid rains, iron rusts faster. On the other hand, alkalis inhibit rusting.
  • Salt: Iron tends to rust faster in sea, due to the presence of salt.
  • Impurity: Pure iron rusts slower than the iron mass which contains a mixture of metals.

Why Rust Prevention?

Rusting makes iron flaky and friable and decreases its intended usage period. The strength, appearance and permeability degrade which leaves the rusted iron useless. A considerable amount of damage is done by rusting every year, which includes damaging of cars, grills, buses, railings, sinking of ships, falling of bridges, deterioration of statues, etc. Huge sums of money is spent for the replacement and repair of these damages. Thus, it is important to take steps to prevent iron from getting rusted.

Preventive Measures

As we have seen earlier, the prime cause of rusting is the exposure of iron to water and air. So, if we don’t let the surface of iron to come in direct contact with them, we can prevent rusting. Some effective measures used to prevent rusting are:

  • Coating and painting: Iron surface is often painted with the coatings of varnish or paint to isolate it from the environment. Window grills, bodies of automobiles, iron bridges and rails are painted regularly to protect them from rusting.
  • Applying a layer of grease: Grease or a layer of oil is also applied to iron surfaces, primarily on machines and industry tools. This serves dual purpose of a lubricant reducing friction as well as rust prevention.
  • Galvanisation: It is a process of depositing a thin layer of a non-reactive metal like zinc on the surface of iron. This metallic layer prevents the iron to come in contact with air and moisture. Buckets, drums, roofs, pipes etc. are galvanized to prevent rusting.
Rusting

Galvanisation of Iron


Practise This Question

In the rusting of Iron, which of the following cell reactions occurs at the anode?