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Question

Match list-I with list-II


Column 1Column 2

Hypophosphorous acid

+5

Orthophosphoric acid

+4

Hypophosphoric acid

+3

Orthophosphorous acid

+1

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Solution

(A) Hypophosphorous acid -(IV) +1

  1. With the chemical formulaH3PO2, hypophosphorous acid, also known as phosphinic acid, is a phosphorus oxyacid and a strong reducing agent.
  2. It is a colorless, low-melting substance that is water soluble.
  3. The oxidation state of phosphorous in H3PO2 will be calculated as let the oxidation state of phosphorus be “x”
  4. Oxidation state=oxidation state of Hydrogen×3+oxidation state of phosphorus+Oxidation state of oxygen×2
  5. Oxidation stat=+1×3+x+(-2)×2
  6. Oxidation state of phosphorous or x=4-3+1

(B) Orthophosphoric acid- (I) +5

  1. The inorganic compound phosphoric acid, also known as orthophosphoric acid, has the formulaH3PO4.
  2. It is a colorless solid.
  3. The oxidation state of phosphorous inH3PO4 will be calculated as let the oxidation state of phosphorus be “x”
  4. Oxidation state=Oxidation state of Hydrogen×3+Oxidation state of phosphorus+Oxidation state of oxygen×4
  5. Oxidation state=+1×3+x+(-2)×4
  6. Oxidation state of phosphorous orx=+5

(C) Hypophosphoric acid-(II) +4

  1. Mineral acid hypophosphoric acid has the formulaH4P2O6
  2. It is a white solid.
  3. The oxidation state of phosphorous inH4P2O6 will be calcuatcalculated the oxidation state of phsophophosphorus
  4. Oxidation state=oxidation state of hydrogen×4+oxidation state of phosphorus×2+Oxidation state of oxygen×4
  5. Oxidation state=+1×4+2x+(-2)×6
  6. Oxidation state of phosphorous or x=+4

(D) Orthophosphorous acid- (III) +3

  1. Orthophosphorous acid or phosphorous acid is the name given toH3PO3.
  2. Salts called phosphites, which are produced by phosphoric acid H3PO3 and are sometimes utilized as reduction agents.
  3. The oxidation state of phosphorous inH3PO3 will be calculated as let the oxidation state of phosphorus be “x”
  4. Oxidation state=oxidation state of Hydrogen×3+oxidation state of phosphorus+Oxidation state of oxygen×3
  5. Oxidation state=+1x3+x+(-2)x3=+1×3+x+(-2)×3
  6. Oxidation state of phosphorous or x=+3

Final answer:

Name of oxo acid

Oxidation state of phosphorous

A. Hypophosphorous acid +1
B. Orthophosphoric acid +5
C. Hypophosphoric acid)+4
D. Orthophosphorous acid+3

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