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Question

The correct order of conductivity of ions in water is:

A

Cs+>Rb+>K+>Na+

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B

K+>Na+>Cs+>Rb+

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C

Rb+>Na+>K+>Li+

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D

Na+>K+>Rb+>Cs+

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Solution

The correct option is A

Cs+>Rb+>K+>Na+


Answer: (a)

Hydration of M+ alkali metals decrease down the group.
Hence, sodium is highly hydrated and cesium is less hydrated.
Since, Cs+(aq) has a lower hydrated radius it is free to move so its electrical conductivity is higher.


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