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Question

Two ideal polyatomic gases at temperatures T1 and T2 are mixed so that there is no loss of energy. If F1 and F2, m1 and m2, n1 and n2 be the degrees of freedom, masses, the number of molecules of the first and second gas respectively, the temperature of the mixture of these two gases is:


A

n1F1T1+n2F2T2n1F1+n2F2

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B

n1F1T1+n2F2T2F1+F2

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C

n1F1T1+n2F2T2n1+n2

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D

n1T1+n2T2n1+n2

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Solution

The correct option is A

n1F1T1+n2F2T2n1F1+n2F2


Step 1: Given

Change in internal energy: U=0 (since there in no loss of energy)

Temperature of first gas is T1

Temperature of second gas is T2

Degree of freedom of first gas is F1

Degree of freedom of second gas is F2

Mass of first gas is m1

Mass of second gas is m2

Number of molecules of first gas is n1

Number of molecules of second gas is n2

Assume the final temperature of the mixture to be T

Step 2: Formula Used

Internal energy of a gas is given by

U=nFkT2

Where, n is the number of moles, F is the degree of freedom, k is the Boltzmann's constant and T is the temperature.

Step 3: Find the temperature of the mixture

Since there is no loss of internal energy, sum of initial internal energies will be equal to final internal energies

U1initial+U2initial=U1final+U2finaln1F1kT12+n2F2kT22=n1F1kT2+n2F2kT2n1F1T1+n2F2T2=n1F1T+n2F2T

Solve the above equation for the final temperature

n1F1T+n2F2T=n1F1T1+n2F2T2Tn1F1+n2F2=n1F1T1+n2F2T2T=n1F1T1+n2F2T2n1F1+n2F2

Hence, the correct option is option A.


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