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Question

Why emulsion is thermodynamically unstable?


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Solution

Emulsion:

  1. A mixture of two or more liquids that which are normally immiscible owing to liquid-liquid phase separation.
  2. In short, in an emulsion, one liquid is dispersed in the other.
  3. Thermodynamic instability means that a system exists is not at equilibrium.

Emulsion is thermodynamically unstable because:

  1. There is a natural tendency for a liquid or a liquid separate.
  2. As they get separated, the interfacial area of it gets reduced.
  3. Apparently, its interfacial energy also gets reduced.

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