0.01M solution of KCl and BaCl2 are prepared in water. The freezing point of KCl is found to be −2∘C. What is the freezing point of BaCl2 to be completely ionised?
A
−3∘C
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B
+3∘C
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C
−2∘C
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D
−4∘C
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Solution
The correct option is A−3∘C △Tf∝i$ ∴△TfforKCl△TfforBaCl2=iforKCliforBaCl2 ∴△TfforKCl△TfforBaCl2=23(∵△Tf for KCl=2) ∴△Tf for BaCl2=3×22=3 ∴ Freezing point of BaCl2=−3∘C