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Question

0.02 mole of [Co(NH3)5Br]Cl2 and 0.02 mole of [Co(NH3Cl]SO4 are present in 200ccof a solution X.The number of moles of the ppt's Yand Z that are formed when the solution X is treated with excess silver nitrate and excess barium chloride are resp

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Solution

0.04moles and 0.02moles.
0.02 moles of [Co(NH3)5Br]Cl2 contain 0.04moles of Cl- ions and hence 0.04 moles of Y are formed on treatment with silver nitrate.
0.02moles of [Co(NH3Cl]SO4 contain 0.02 moles of SO42- ions and hence 0.02moles of Z are formed on treatment with barium chloride.

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